Airborne measurements of BrO and the sum of HOBr and Br2 over the Tropical West Pacific from 1 to 15 km during the CONvective TRansport of Active Species in the Tropics (CONTRAST) experiment
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Type of Work19 pages
Citation of Original PublicationChen, D., et al. (2016), Airbornemeasurements of BrO and the sum ofHOBr and Br2over the Tropical WestPaciﬁc from 1 to 15 km during theCONvective TRansport of Active Speciesin the Tropics (CONTRAST) experiment,J. Geophys. Res. Atmos., 121,12,560–12,578, doi:10.1002/2016JD025561.
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A chemical ionization mass spectrometer was used to measure BrO and HOBr + Br₂ over the Tropical West Pacific Ocean within the altitude range of 1 to 15 km, during the CONvective TRansport of Active Species in the Tropics (CONTRAST) campaign in 2014. Isolated episodes of elevated BrO (up to 6.6 pptv) and/or HOBr + Br₂ (up to 7.3 pptv) were observed in the tropical free troposphere (TFT) and were associated with biomass burning. However, most of the time we did not observe significant BrO or HOBr + Br₂ in the TFT and the tropical tropopause layer (TTL) above our limits of detection (LOD). The 1 min average LOD for BrO ranged from 0.6 to 1.6 pptv and for HOBr + Br₂ ranged from 1.3 to 3.5 pptv. During one flight, BrO observations from the TTL to the extratropical lowermost stratosphere were used to infer a profile of inorganic bromine (Bry). Based on this profile, we estimated the product gas injection of bromine species into the stratosphere to be 2 pptv. Analysis of Bry partitioning further indicates that BrO levels are likely very low in the TFT environment and that future studies should target the measurement of HBr or atomic Br.
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