Fixed-angle observation of surface plasmon coupled chemiluminescence from palladium thin films

Date

2009-09-25

Department

Program

Citation of Original Publication

Aslan, Kadir, Micah Weisenberg, Elinor Hortle, and Chris D. Geddes. “Fixed-Angle Observation of Surface Plasmon Coupled Chemiluminescence from Palladium Thin Films.” Applied Physics Letters 95, no. 12 (September 25, 2009): 123117. https://doi.org/10.1063/1.3236773.

Rights

This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing. This article appeared in Aslan, Kadir, Micah Weisenberg, Elinor Hortle, and Chris D. Geddes. “Fixed-Angle Observation of Surface Plasmon Coupled Chemiluminescence from Palladium Thin Films.” Applied Physics Letters 95, no. 12 (September 25, 2009): 123117. https://doi.org/10.1063/1.3236773. and may be found at https://pubs.aip.org/aip/apl/article/95/12/123117/338073/Fixed-angle-observation-of-surface-plasmon-coupled.

Subjects

Abstract

In this letter, the fixed-angle observation of surface plasmon coupled chemiluminescence (SPCC) from palladium thin films is reported. Fresnel calculations predict that light 492–549 nm spectral range can efficiently induce surface plasmon modes in 15 nm palladium thin films. Free-space emission from blue, green, and chartreuse chemiluminescent solutions on palladium thin films was isotropic, while the SPCC emission was highly directional and predominantly p-polarized in accordance with the predictions of the Fresnel calculations. In addition, the decay rates of the SPCC and free-space emission were similar, which suggests that palladium thin films have no catalytic effect on chemiluminescence emission.