Paradigms and paradoxes: what is the enthalpy of formation of triglycine or should we have asked “What are the enthalpies of formation of the triglycines”?

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dc.contributor.authorPerisanu, Stefan
dc.contributor.authorPonikvar-Svet, Maja
dc.contributor.authorEdwards, Kathleen Frances
dc.contributor.authorLiebman, Joel F.
dc.date.accessioned2025-11-21T00:30:08Z
dc.date.issued2025-10-11
dc.description.abstractThe current paper discusses the enthalpy of formation of triglycine. Upon asking “What is the enthalpy of formation of triglycine?”, we find that there are two non-isomeric species that are generally referred to as “triglycine”: glycylglycylglycine and nitrilotriacetic acid. In the current paper the enthalpies of formation of these two species termed "triglycines" are discussed and related to each other. In addition, a similar analysis is carried out for the related “diglycines”.
dc.description.sponsorshipMPS gratefully acknowledges the Slovenian Research and Innovation Agency (ARIS Grant P1-0045, Inorganic Chemistry and Technology) for financial support.
dc.description.urihttps://link.springer.com/article/10.1007/s11224-025-02624-1
dc.format.extent5 pages
dc.genrejournal articles
dc.identifierdoi:10.13016/m28uon-e819
dc.identifier.citationPerisanu, Stefan, Maja Ponikvar-Svet, Kathleen Frances Edwards, and Joel Fredric Liebman. “Paradigms and Paradoxes: What Is the Enthalpy of Formation of Triglycine or Should We Have Asked ‘What Are the Enthalpies of Formation of the Triglycines’?” Structural Chemistry, ahead of print, October 11, 2025. https://doi.org/10.1007/s11224-025-02624-1.
dc.identifier.urihttps://doi.org/10.1007/s11224-025-02624-1
dc.identifier.urihttp://hdl.handle.net/11603/40844
dc.language.isoen
dc.publisherSpringer Nature
dc.relation.isAvailableAtThe University of Maryland, Baltimore County (UMBC)
dc.relation.ispartofUMBC Chemistry & Biochemistry Department
dc.relation.ispartofUMBC Faculty Collection
dc.rightsAttribution 4.0 International
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectGlycine
dc.subjectDiglycines, enthalpies of formation, fusion and of reaction
dc.subjectGlycylglycylglycine
dc.subjectNitrilotriacetic acid
dc.subjectTriglycine(s)
dc.subject?-amino acids
dc.titleParadigms and paradoxes: what is the enthalpy of formation of triglycine or should we have asked “What are the enthalpies of formation of the triglycines”?
dc.typeText
dcterms.creatorhttps://orcid.org/0000-0001-6119-7132
dcterms.creatorhttps://orcid.org/0000-0002-6109-7753

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