Synthesis of 3-hetarylpyrroles by Suzuki–Miyaura cross-coupling
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Matyugina, Elena S., Anastasia L. Khandazhinskaya, Sergey N. Kochetkov, and Katherine L. Seley-Radtke. “Synthesis of 3-Hetarylpyrroles by Suzuki–Miyaura Cross-Coupling.” Mendeleev Communications 30, no. 2 (March 1, 2020): 231–32. https://doi.org/10.1016/j.mencom.2020.03.034.
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Abstract
1-[tert-Butyl(diphenyl)silyl]pyrrol-3-ylboronic acid was obtained from pyrrole in three steps. Its Suzuki–Miyaura cross-coupling with functionalized pyridinyl and pyrimidinyl bromides afforded new promising 3-hetaryl-1H-pyrroles.