A systematic comparison of ACE-FTS δD retrievals with airborne in situ sampling
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Author/Creator ORCID
Date
2025-04-04
Type of Work
Department
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Citation of Original Publication
Clouser, Benjamin Wade, Carly Cyd KleinStern, Adrien Desmoulin, Clare E. Singer, Jason M. St. Clair, Thomas F. Hanisco, David S. Sayres, and Elisabeth J. Moyer. “A Systematic Comparison of ACE-FTS δD Retrievals with Airborne in Situ Sampling.” EGUsphere, April 4, 2025, 1–25. https://doi.org/10.5194/egusphere-2025-1190.
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This work was written as part of one of the author's official duties as an Employee of the United States Government and is therefore a work of the United States Government. In accordance with 17 U.S.C. 105, no copyright protection is available for such works under U.S. Law.
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Public Domain
Abstract
The isotopic composition of water vapor in the upper troposphere and lower stratosphere (UTLS) can be used to understand and constrain the budget and pathways of water transport into that region of the atmosphere. Measurements of the water isotopic composition help further understanding of the region's chemistry, radiative budget, and the sublimation and growth of polar stratospheric clouds and high-altitude cirrus, both of which are also important to stratospheric chemistry and Earth's radiation budget. Here we present the first intercomparison of water isotopic composition δD using in situ measurements from the ChiWIS, Harvard ICOS, and Hoxotope instruments and satellite retrievals from ACE-FTS. The in situ data comes from the AVE-WIIF, TC4, CR-AVE, StratoClim, and ACCLIP field campaigns, and satellite retrievals of isotopic composition are derived from the ACE-FTS v5.2 data set. We find that in all campaign intervals, the satellite retrievals above about 14 km altitude are depleted by up to 150 ‰ with respect to in situ measurements. We also use in situ measurements from the ChiWIS instrument, which has flown in both the Asian Summer Monsoon (AM) and the North American Monsoon (NAM), to confirm the isotopic enhancement in δD observed in satellite retrievals above the NAM.