The linkage between optical and electrochemical properties of V₂O₅ cathodes during cycling in aqueous Zn-ion batteries using wide-field reflectivity

dc.contributor.authorMaclennan, Hunter
dc.contributor.authorMarckx, Bret
dc.contributor.authorCapraz, Ömer Özgür
dc.date.accessioned2025-09-18T14:22:19Z
dc.date.issued2025-08-19
dc.description.abstractUnderstanding dynamic processes in battery materials under real-time conditions is critical for advancing electrochemical storage technologies. Here, we develop an operando optical technique to probe changes in the wide-field reflectance of vanadium oxide cathodes during cycling in aqueous Zn-ion batteries by using a budget-friendly experimental setup and lab-made Python code. The results indicate that brightness of the vanadium oxide was dramatically changed with intercalation process at certain states-of-(dis)charge. Our methodology correlates wide-field reflectance changes with electrochemical behavior, enabling operando monitoring of the materials' evolution in aqueous battery systems.
dc.description.sponsorshipThis work was supported by the start-up grant at the University of Maryland Baltimore County. H.M. was supported by the National Science Foundation Research Experiences for Undergraduates (REU) program, award #2050728.
dc.description.urihttps://link.springer.com/article/10.1557/s43579-025-00792-z
dc.format.extent6 pages
dc.genrejournal articles
dc.identifierdoi:10.13016/m2mcys-vkxy
dc.identifier.citationMaclennan, Hunter, Bret Marckx, and Ömer Özgür Capraz. “The Linkage between Optical and Electrochemical Properties of V₂O₅ Cathodes during Cycling in Aqueous Zn-Ion Batteries Using Wide-Field Reflectivity.” MRS Communications, August 19, 2025. https://doi.org/10.1557/s43579-025-00792-z.
dc.identifier.urihttps://doi.org/10.1557/s43579-025-00792-z
dc.identifier.urihttp://hdl.handle.net/11603/40226
dc.language.isoen
dc.publisherSpringer Nature
dc.relation.isAvailableAtThe University of Maryland, Baltimore County (UMBC)
dc.relation.ispartofUMBC Chemical, Biochemical & Environmental Engineering Department
dc.relation.ispartofUMBC Student Collection
dc.relation.ispartofUMBC Faculty Collection
dc.rightsAttribution 4.0 International
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectChemical reaction
dc.subjectOptical properties
dc.subjectStress/strain relationship
dc.subjectComposite
dc.titleThe linkage between optical and electrochemical properties of V₂O₅ cathodes during cycling in aqueous Zn-ion batteries using wide-field reflectivity
dc.typeText
dcterms.creatorhttps://orcid.org/0009-0005-8624-187X
dcterms.creatorhttps://orcid.org/0009-0004-4092-7190
dcterms.creatorhttps://orcid.org/0000-0002-2396-4748

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